Carbon, C (Graphite)

Carbon is a chemical element with the symbol C and atomic number 6. It is a group 14, nonmetallic, tetravalent element, that presents several allotropic forms of which the best known are graphite (the thermodynamically stable form under normal conditions), diamond, and amorphous carbon. There are three naturally occurring isotopes: 12C and 13C are stable, and 14C is radioactive, decaying with a half-life of about 5700 years. Carbon is one of the few elements known to man since antiquity. The name "carbon" comes from Latin language carbo, coal, and in some Romance languages, the word carbon can refer both to the element and to coal.

It is the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. It is present in all known lifeforms, and in the human body it is the second most abundant element by mass (about 18.5%) after oxygen. This abundance, together with the unique diversity of organic compounds and their unusual polymer-forming ability at the temperatures commonly encountered on Earth, make this element the chemical basis of all known life.

The physical properties of carbon vary widely with the allotropic form. For example, diamond is highly transparent, while graphite is opaque and black. Diamond is among the hardest materials known, while graphite is soft enough to form a streak on paper. Diamond has a very low electric conductivity, while graphite is a very good conductor. Also, diamond has the highest thermal conductivity of all known materials under normal conditions. All the allotropic forms are solids under normal conditions.

All forms of carbon are highly stable, requiring high temperature to react even with oxygen. The most common oxidation state of carbon in inorganic compounds is +4, while +2 is found in carbon monoxide and other transition metal carbonyl complexes. The largest sources of inorganic carbon are limestones, dolomites and carbon dioxide, but significant quantities occur in organic deposits of coal, peat, oil and methane clathrates. Carbon forms more compounds than any other element, with almost ten million pure organic compounds described to date, which in turn are a tiny fraction of such compounds that are theoretically possible under standard conditions.

Technical Data
Symbol C Density (20°C)/gcm 3.514
Atomic number 6 Melting point /°C 4100
No. of naturally occurring isotopes 2+1 Boiling point /°C -
Atomic weight 12.011 ΔHf(monoatomic gas)/kJmol-1 716.7
Electronic configuration [He] 2s22p2 Electrical resistivity  
Ionization energy/kJmol-1 1086.1 (20°C)/ μohm cm 1014-1016
II 2351.9 Band gap Eg/kJ mol-1 ~580
III 4618.8 rVI(covalent)/pm 77.2
IV 6221 r VI (ionic,6-coordinate)/pm (15) (CN4)
Electronegativity χ 2.5    
Evaporation Techniques
Temperature (oC) @Vap. Pressure Techniques Remarks
10-8 Torr 10-6 Torr 10-4 Torr Electron Beam Crucible Coil Boat
1657 Sublimes 1867 Sublimes 2137 Sublimes Excellent - - - EB preferred. Arc evaporation. Poor film Adhesion. Vitreous carbon n= 1.47.

Powder
C3-10000-P -100 mesh
C3-10001-P -200 mesh
C3-10002-P -325 mesh
Rods
C3-2001-R 0.125" (3.175mm)
C3-2003-R 0.250" (6.35mm)
C3-2005-R 0.375" (9.5mm)
C3-20006-R 0.394" (10mm)
C3-2007-R 0.500" (12.7mm)
C3-2008-R 0.625" (15.8mm)
C3-2009-R 0.750" (19mm)
C3-2010-R 1" (25.4mm)
C3-2012-R 1.5" (38.1mm)
C3-2014-R 2" (50.8mm)
C3-2016-R 3" (76.2mm)
C3-2017-R 4" (101.6mm)
C3-2018-R 5" (127mm)
C3-2019-R 6" (152.4mm)
Sheet
C3-4002-S 0.015" (0.38mm)
C3-4003-S 0.020" (0.5mm)
C3-4005-S 0.050" (1.2mm)
C3-4006-S 0.125" (3.175")
C3-4008-S 0.250" (6.35mm)
C3-4009-S 0.375" (9.25mm)
C3-4010-S 0.500" (12.7mm)
C3-4011-S 2" (50.8mm)
C3-4012-S 4" (101.6mm)
C3-4013-S 1" (25.4mm)